Photon Upconversion Through Tb(3+) -Mediated Interfacial Energy Transfer.

Enabling Photon Upconversion and Precise Control of Donor–Acceptor Interaction through Interfacial Energy Transfer

Upconverting materials have achieved great progress in recent years, however, it remains challenging for the mechanistic research on new upconversion strategy of lanthanides. Here, a novel and efficient strategy to realize photon upconversion from more lanthanides and fine control of lanthanide donor-acceptor interactions through using the interfacial energy transfer (IET) is reported. Unlike c...

Controlling Upconversion: Enabling Photon Upconversion and Precise Control of Donor–Acceptor Interaction through Interfacial Energy Transfer (Adv. Sci. 3/2018)

Tuning upconversion through energy migration in core-shell nanoparticles.

Photon upconversion is promising for applications such as biological imaging, data storage or solar cells. Here, we have investigated upconversion processes in a broad range of gadolinium-based nanoparticles of varying composition. We show that by rational design of a core-shell structure with a set of lanthanide ions incorporated into separated layers at precisely defined concentrations, effic...

Energy Transfer Upconversion

The usual fluorescence behavior follows Stokes law, where exciting photons are of higher energy than emitted photons. Anti-Stokes processes usually concern emitted energies in excess of excited energies by only a few kT. These processes include anti-Stokes emission by the thermal bands or by the Raman effect. There are processes, however, in which emission photon energy exceeds excited photon e...

Energy transfer in lanthanide upconversion studies for extended optical applications.

Lanthanide pairs, which can upconvert low energy photons into higher energy photons, are promising for efficient upconversion emission. A typical system with Yb(3+) as a sensitizer can convert short NIR into visible/ultraviolet light via energy transfer between lanthanide ions. Such upconverting nanocrystals doped with lanthanide ions have found significant potential in bioimaging, photochemica...